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• W2022175624 abstract "The inclusion compounds of α-, β- and γ-cyclodextrins (α-CD, β-CD and γ-CD) with trans-cinnamic acid (t-CIA), 3-hydroxy-trans-cinnamic acid (t-3OHCIA), 4-hydroxy-trans-cinnamic acid (t-4OHCIA) and 3,4-dihydroxy-trans-cinnamic acid (t-3,4OHCIA) were prepared and characterized, in the solid state, by means of thermogravimetry and Raman spectroscopy. The effects of the inclusion process on the guest molecules and on the hydrogen bond interactions of the guest were studied by monitoring sensitive vibrational modes, such as CO, CC and ring CH stretching modes. By combining Raman and TG data with ab initio calculations and information from CSD database on similar compounds, inclusion geometries for the different compounds are proposed. The size of the host cavity and the maximization of host/guest hydrogen-bonding contacts appear to be the main factors determining the inclusion geometries. Copyright © 2009 John Wiley & Sons, Ltd." @default.
• W2022175624 created "2016-06-24" @default.
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• W2022175624 date "2009-06-01" @default.
• W2022175624 modified "2023-09-25" @default.
• W2022175624 title "Spectroscopic and thermal studies on the inclusion oftrans-cinnamic acid and a number of its hydroxyl-derivatives with α, β and γ-cyclodextrins molecules" @default.
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• W2022175624 doi "https://doi.org/10.1002/jrs.2182" @default.
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