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- W2022178998 abstract "Abstract The reaction of β-lactam carbenes with alkyl isonitriles was investigated. Two different types of products, 4-cyano- or 4-carbamoyl-β-lactams, were isolated, depending upon the nature of the alkyl group of the isonitriles. The cyano-β-lactams were derived by a N-to-C 1,3-rearrangement of the ketenimine intermediates, while the carbamoyl-β-lactams were the hydrolysis products of the intermediates. This work extends the application of β-lactam carbenes, and provides a very simple and efficient route to 4-cyano- or 4-carbamoyl-β-lactams, which are versatile synthetic intermediates and new chemical entities of potential biological activity." @default.
- W2022178998 created "2016-06-24" @default.
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- W2022178998 date "2007-12-18" @default.
- W2022178998 modified "2023-09-23" @default.
- W2022178998 title "Reaction of β-Lactam Carbenes with Alkyl Isonitriles for a Ready Approach to 4-Cyano and 4-Carbamoyl Substituted β-Lactams." @default.
- W2022178998 cites W2951377180 @default.
- W2022178998 doi "https://doi.org/10.1002/chin.200751140" @default.
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