Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022180138> ?p ?o ?g. }
- W2022180138 endingPage "2805" @default.
- W2022180138 startingPage "2798" @default.
- W2022180138 abstract "A chiral self-assembled M4L6 host assembly has been shown to be a suitable host for the supramolecular encapsulation of a series of guests in polar solvents, ranging from simple organic ammonium cations to more complex organometallic species. This molecular recognition process creates highly selective reactivity within the host cavity. In order to understand the factors driving the molecular recognition process, the standard thermodynamic parameters for encapsulation were determined for a series of protiated and fluorinated iridium guests in a variety of polar solvents using van't Hoff analysis. The encapsulation process for these guests exhibited enthalpy−entropy compensation effects. In solvents such as water and methanol, error analysis suggests a chemical origin for this behavior. In contrast, error analysis of this compensation behavior in polar aprotic solvents such as dimethyl sulfoxide reveals that this correlation is due to an artifact inherent in the intrinsic correlation between the enthalpy and entropy terms in the van't Hoff analysis. Guest encapsulation in polar protic solvents such as water appears to be driven by initial desolvation of the guest with concomitant rearrangement of the hydrogen bond networks in solution. This behavior shares common characteristics with other synthetic and natural host−guest and molecular recognition processes in aqueous solution, ranging from simple crown ether to complex enzyme−ligand interactions." @default.
- W2022180138 created "2016-06-24" @default.
- W2022180138 creator A5000036143 @default.
- W2022180138 creator A5047518475 @default.
- W2022180138 creator A5073204417 @default.
- W2022180138 date "2008-02-08" @default.
- W2022180138 modified "2023-10-15" @default.
- W2022180138 title "Enthalpy−Entropy Compensation Reveals Solvent Reorganization as a Driving Force for Supramolecular Encapsulation in Water" @default.
- W2022180138 cites W1964859294 @default.
- W2022180138 cites W1966145600 @default.
- W2022180138 cites W1977016804 @default.
- W2022180138 cites W1980316342 @default.
- W2022180138 cites W1983899252 @default.
- W2022180138 cites W1988443675 @default.
- W2022180138 cites W2002660032 @default.
- W2022180138 cites W2016628473 @default.
- W2022180138 cites W2024506025 @default.
- W2022180138 cites W2026778491 @default.
- W2022180138 cites W2031164685 @default.
- W2022180138 cites W2048239066 @default.
- W2022180138 cites W2060816361 @default.
- W2022180138 cites W2061119072 @default.
- W2022180138 cites W2066708133 @default.
- W2022180138 cites W2066988778 @default.
- W2022180138 cites W2071722811 @default.
- W2022180138 cites W2074679855 @default.
- W2022180138 cites W2076544185 @default.
- W2022180138 cites W2077179637 @default.
- W2022180138 cites W2082308337 @default.
- W2022180138 cites W2083331450 @default.
- W2022180138 cites W2084087156 @default.
- W2022180138 cites W2087546857 @default.
- W2022180138 cites W2087571702 @default.
- W2022180138 cites W2092687179 @default.
- W2022180138 cites W2122773909 @default.
- W2022180138 cites W2124461002 @default.
- W2022180138 cites W2126208045 @default.
- W2022180138 cites W2126836775 @default.
- W2022180138 cites W2130892744 @default.
- W2022180138 cites W2321283660 @default.
- W2022180138 cites W2333283056 @default.
- W2022180138 cites W29179573 @default.
- W2022180138 cites W2949376410 @default.
- W2022180138 cites W4244914404 @default.
- W2022180138 doi "https://doi.org/10.1021/ja075975z" @default.
- W2022180138 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18257565" @default.
- W2022180138 hasPublicationYear "2008" @default.
- W2022180138 type Work @default.
- W2022180138 sameAs 2022180138 @default.
- W2022180138 citedByCount "147" @default.
- W2022180138 countsByYear W20221801382012 @default.
- W2022180138 countsByYear W20221801382013 @default.
- W2022180138 countsByYear W20221801382014 @default.
- W2022180138 countsByYear W20221801382015 @default.
- W2022180138 countsByYear W20221801382016 @default.
- W2022180138 countsByYear W20221801382017 @default.
- W2022180138 countsByYear W20221801382018 @default.
- W2022180138 countsByYear W20221801382019 @default.
- W2022180138 countsByYear W20221801382020 @default.
- W2022180138 countsByYear W20221801382021 @default.
- W2022180138 countsByYear W20221801382022 @default.
- W2022180138 countsByYear W20221801382023 @default.
- W2022180138 crossrefType "journal-article" @default.
- W2022180138 hasAuthorship W2022180138A5000036143 @default.
- W2022180138 hasAuthorship W2022180138A5047518475 @default.
- W2022180138 hasAuthorship W2022180138A5073204417 @default.
- W2022180138 hasConcept C112887158 @default.
- W2022180138 hasConcept C121332964 @default.
- W2022180138 hasConcept C147789679 @default.
- W2022180138 hasConcept C178790620 @default.
- W2022180138 hasConcept C179303850 @default.
- W2022180138 hasConcept C184651966 @default.
- W2022180138 hasConcept C185592680 @default.
- W2022180138 hasConcept C2780471494 @default.
- W2022180138 hasConcept C3288061 @default.
- W2022180138 hasConcept C32909587 @default.
- W2022180138 hasConcept C93275456 @default.
- W2022180138 hasConcept C97355855 @default.
- W2022180138 hasConceptScore W2022180138C112887158 @default.
- W2022180138 hasConceptScore W2022180138C121332964 @default.
- W2022180138 hasConceptScore W2022180138C147789679 @default.
- W2022180138 hasConceptScore W2022180138C178790620 @default.
- W2022180138 hasConceptScore W2022180138C179303850 @default.
- W2022180138 hasConceptScore W2022180138C184651966 @default.
- W2022180138 hasConceptScore W2022180138C185592680 @default.
- W2022180138 hasConceptScore W2022180138C2780471494 @default.
- W2022180138 hasConceptScore W2022180138C3288061 @default.
- W2022180138 hasConceptScore W2022180138C32909587 @default.
- W2022180138 hasConceptScore W2022180138C93275456 @default.
- W2022180138 hasConceptScore W2022180138C97355855 @default.
- W2022180138 hasIssue "9" @default.
- W2022180138 hasLocation W20221801381 @default.
- W2022180138 hasLocation W20221801382 @default.
- W2022180138 hasOpenAccess W2022180138 @default.
- W2022180138 hasPrimaryLocation W20221801381 @default.
- W2022180138 hasRelatedWork W1483052854 @default.
- W2022180138 hasRelatedWork W1926189046 @default.
- W2022180138 hasRelatedWork W2069773251 @default.