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- W2022180697 abstract "Because of the theoretically impossible structure of these bands as reported by previous observers, the writers have measured them, in absorption, in the third order spectrum of a seven inch plane grating mounted in a forty foot spectrograph. Each band is found, quite definitely, to consist of only one $P$, one $Q$ and one $R$ branch. This accords with Mulliken's theory that the electronic transition is $^{1}Pensuremath{-}^{1}S$, and with the nature of the fluorescence series. Moreover the absorption series correlate properly with the fluorescence series. The combination relations have been applied to all measured bands and found to hold, rigorously, within the experimental error, except for the expected $mathrm{PQR}$ defect, which is very small.Constants of the band system.---The more important constants of this band system are: ${{B}_{0}}^{ensuremath{'}ensuremath{'}}=0.15431$, ${{I}_{0}}^{ensuremath{'}ensuremath{'}}=179.5ifmmodetimeselsetexttimesfi{}{10}^{ensuremath{-}40}mathrm{g}$. ${mathrm{cm}}^{2}$, ${{r}_{0}}^{ensuremath{'}ensuremath{'}}=3.08ifmmodetimeselsetexttimesfi{}{10}^{ensuremath{-}8}$ cm, ${ensuremath{alpha}}^{ensuremath{'}ensuremath{'}}=0.00082$, ${{B}_{0}}^{ensuremath{'}}=0.12541$, ${{I}_{0}}^{ensuremath{'}}=220.9ifmmodetimeselsetexttimesfi{}{10}^{ensuremath{-}40}$ g. ${mathrm{cm}}^{2}$, ${{r}_{0}}^{ensuremath{'}}=3.41ifmmodetimeselsetexttimesfi{}{10}^{ensuremath{-}8}$ cm, ${ensuremath{alpha}}^{ensuremath{'}}=0.00094$. These extremely large internuclear distances correspond to weak molecular binding, which is in accord with the low heat of dissociation previously reported. The locus of most intense vibrational transitions calculated from these constants and the previously reported vibrational constants, by the method of Franck and Condon, is found to be a good representation of the observed distribution. There is no evidence of alternating intensities." @default.
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- W2022180697 title "The Rotational Structure of the Blue-Green Bands of<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>Na</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>" @default.
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- W2022180697 doi "https://doi.org/10.1103/physrev.32.223" @default.
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