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- W2022182141 endingPage "1969" @default.
- W2022182141 startingPage "1969" @default.
- W2022182141 abstract "E.s.r. spectra of radicals derived by addition of several alkali-metals to 1,2-bispentamethylbenzoyl-, 1,2-dimesitoyl-, 1-benzoyl-2-mesitoyl-, and 1,2,4,5-tetramesitoyl-benzene were studied in nine aprotic solvents. The electron spin densities at the alkali-metal obtained from the experimental alkalimetal couplings together with previously published values (12 solvents combined with Li, Na, K, Rb, and Cs) correlate linearly with the empirical solvent parameters ETN(30) and DN, and with the radius of the alkali cation. This is interpreted as a consequence of the interionic distance being controlled by dipolarity and Lewis basicity of the solvent, along with the cation radius." @default.
- W2022182141 created "2016-06-24" @default.
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- W2022182141 date "1988-01-01" @default.
- W2022182141 modified "2023-09-25" @default.
- W2022182141 title "Influence of solvent and cation on the properties of oxygen-containing organic anions. Part 3. Electron spin density on alkali-metal cations chelated by radical anions as a function of interionic distance" @default.
- W2022182141 doi "https://doi.org/10.1039/p29880001969" @default.
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