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- W2022182524 abstract "We have studied the CO chemisorption properties of small two-dimensional clusters (islands) and of monolayers and multilayers of cobalt deposited on Cu(100). The behaviour of one monolayer of cobalt is indistinguishable from the multilayers indicating weak influence of the copper support twoards the adsorption of CO. Below one monolayer of cobalt we observed the appearance of new peaks in the thermal desorption spectrum of CO related to the increasingly large number of edge atoms and small size of the cobalt islands. Of particular interest is the number of CO molecules bound per cobalt atom as a function of island size. This number was found to vary from 0.65, with the compression structure formed on the monolayer and multilayer cobalt coverages, up to approximately 3 when the cobalt coverage decreased to 0.002 monolayers." @default.
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- W2022182524 date "1984-07-01" @default.
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- W2022182524 title "CO chemisorption on two-dimensional cobalt clusters: A surface science approach to cluster chemistry" @default.
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- W2022182524 doi "https://doi.org/10.1016/0039-6028(84)90426-6" @default.
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