Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022185780> ?p ?o ?g. }
- W2022185780 abstract "Protection of metal nanoparticles from agglomeration is critical for their functions and applications. The conventional method for enhancing their stability is to cover them with passivation layers to prevent direct contact. However, the presence of a protective shell blocks exposure of the metal species to reactants, thereby significantly impeding the nanoparticles' utility as catalysts. Here, we report that metal nanoparticles can be prepared and used in a surface-exposed state that renders them inherently catalytically active. This strategy is realised by spatial confinement and electronic stabilisation with a dual-module mesoporous and microporous three-dimensional π-network in which surface-exposed nanoparticles are crystallised upon in situ reduction. The uncovered palladium nanoparticles serve as heterogeneous catalysts that are exceptionally active in water, catalyse unreactive aryl chlorides for straightforward carbon–carbon bond formation and are stable for repeated use in various types of cross couplings. Therefore, our results open new perspectives in developing practical heterogeneous catalysts." @default.
- W2022185780 created "2016-06-24" @default.
- W2022185780 creator A5010663876 @default.
- W2022185780 creator A5029740208 @default.
- W2022185780 creator A5084176696 @default.
- W2022185780 date "2014-11-27" @default.
- W2022185780 modified "2023-09-26" @default.
- W2022185780 title "High-performance heterogeneous catalysis with surface-exposed stable metal nanoparticles" @default.
- W2022185780 cites W1964297120 @default.
- W2022185780 cites W1965488110 @default.
- W2022185780 cites W1966937884 @default.
- W2022185780 cites W1973051136 @default.
- W2022185780 cites W1976277867 @default.
- W2022185780 cites W1978890358 @default.
- W2022185780 cites W1980106869 @default.
- W2022185780 cites W1991007131 @default.
- W2022185780 cites W2004865495 @default.
- W2022185780 cites W2004867175 @default.
- W2022185780 cites W2011125761 @default.
- W2022185780 cites W2012482444 @default.
- W2022185780 cites W2016899509 @default.
- W2022185780 cites W2016927087 @default.
- W2022185780 cites W2027713965 @default.
- W2022185780 cites W2035887835 @default.
- W2022185780 cites W2035961673 @default.
- W2022185780 cites W2044571535 @default.
- W2022185780 cites W2061788527 @default.
- W2022185780 cites W2064788364 @default.
- W2022185780 cites W2065744294 @default.
- W2022185780 cites W2068058707 @default.
- W2022185780 cites W2071592915 @default.
- W2022185780 cites W2075619400 @default.
- W2022185780 cites W2078820160 @default.
- W2022185780 cites W2087409065 @default.
- W2022185780 cites W2087808523 @default.
- W2022185780 cites W2088977008 @default.
- W2022185780 cites W2104949820 @default.
- W2022185780 cites W2110284330 @default.
- W2022185780 cites W2110599562 @default.
- W2022185780 cites W2113196762 @default.
- W2022185780 cites W2119611880 @default.
- W2022185780 cites W2138177542 @default.
- W2022185780 cites W2141980865 @default.
- W2022185780 cites W2142141141 @default.
- W2022185780 cites W2142416069 @default.
- W2022185780 cites W2142841029 @default.
- W2022185780 cites W2145120220 @default.
- W2022185780 cites W2145592218 @default.
- W2022185780 cites W2146987542 @default.
- W2022185780 cites W2147257319 @default.
- W2022185780 cites W2162784980 @default.
- W2022185780 cites W2324964879 @default.
- W2022185780 cites W2329730416 @default.
- W2022185780 cites W2331255865 @default.
- W2022185780 cites W2334429978 @default.
- W2022185780 cites W2482281523 @default.
- W2022185780 cites W4248401078 @default.
- W2022185780 doi "https://doi.org/10.1038/srep07228" @default.
- W2022185780 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4245523" @default.
- W2022185780 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25427425" @default.
- W2022185780 hasPublicationYear "2014" @default.
- W2022185780 type Work @default.
- W2022185780 sameAs 2022185780 @default.
- W2022185780 citedByCount "46" @default.
- W2022185780 countsByYear W20221857802015 @default.
- W2022185780 countsByYear W20221857802016 @default.
- W2022185780 countsByYear W20221857802017 @default.
- W2022185780 countsByYear W20221857802018 @default.
- W2022185780 countsByYear W20221857802019 @default.
- W2022185780 countsByYear W20221857802020 @default.
- W2022185780 countsByYear W20221857802021 @default.
- W2022185780 countsByYear W20221857802022 @default.
- W2022185780 crossrefType "journal-article" @default.
- W2022185780 hasAuthorship W2022185780A5010663876 @default.
- W2022185780 hasAuthorship W2022185780A5029740208 @default.
- W2022185780 hasAuthorship W2022185780A5084176696 @default.
- W2022185780 hasBestOaLocation W20221857801 @default.
- W2022185780 hasConcept C104779481 @default.
- W2022185780 hasConcept C127413603 @default.
- W2022185780 hasConcept C131850264 @default.
- W2022185780 hasConcept C140205800 @default.
- W2022185780 hasConcept C155672457 @default.
- W2022185780 hasConcept C159985019 @default.
- W2022185780 hasConcept C161790260 @default.
- W2022185780 hasConcept C171250308 @default.
- W2022185780 hasConcept C175583648 @default.
- W2022185780 hasConcept C178790620 @default.
- W2022185780 hasConcept C185592680 @default.
- W2022185780 hasConcept C191897082 @default.
- W2022185780 hasConcept C192562407 @default.
- W2022185780 hasConcept C2779227376 @default.
- W2022185780 hasConcept C33574316 @default.
- W2022185780 hasConcept C42360764 @default.
- W2022185780 hasConcept C502130503 @default.
- W2022185780 hasConcept C544153396 @default.
- W2022185780 hasConcept C82776694 @default.
- W2022185780 hasConcept C86381522 @default.
- W2022185780 hasConceptScore W2022185780C104779481 @default.
- W2022185780 hasConceptScore W2022185780C127413603 @default.
- W2022185780 hasConceptScore W2022185780C131850264 @default.