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- W2022187194 abstract "Series of benzene-in-water microemulsions have been prepared by diluting with the relevant aqueous phase more concentrated microemulsions obtained by means of a valve homogenizer. Tween 20 and Span 20 were used as emulsifiers. Thus each series of microemulsions was characterized by the benzene volume fraction Φi of the “initial concentrated microemulsion, and each microemulsion of a series by its benzene volume fraction Φ (Φ ⩽ Φi). The dielectric behavior of these systems was studied over the frequency range [100 kHz-5 Mhz]. In accord with theoretical predictions, no dielectric dispersion due to interfacial polarization was noticeable over the frequency range concerned, the relative permittivity ϵ′ of any microemulsion being independent of frequency. The permittivity data for the series characterized by the highest value of Φi compatible with the concentration of emulsifier in the aqueous phase were found to conform to the following equation ϵ′ = 32ϵ1′ + (ϵ2′ − 32ϵ1′) (1 − Φ)32 where ϵ1′ is the relative static permittivity of benzene and ϵ2′ that of the aqueous phase employed. For series characterized by smaller Φi the values of ϵ′ are greater than the theoretical ones. These discrepancies might be ascribed to factors such as the structure of the interfacial film surrounding individual droplets and the formation of micelles in the aqueous phase." @default.
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- W2022187194 date "1976-07-01" @default.
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- W2022187194 title "Dielectric properties of benzene-in-water microemulsions in the frequency range 100 kHz-5 Mhz" @default.
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