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- W2022189912 abstract "An efficient, stereocontrolled total synthesis of the complex indole-diterpene alkaloid (−)-21-isopentenylpaxilline (1) has been achieved. Key elements of the synthesis include the stereocontrolled construction of the advanced eastern hemisphere (−)-68, involving a highly efficient union of the eastern and western fragments (−)-68 and 5 exploiting our 2-substituted indole synthesis, application of the Negishi π cycloalkylation tactic as a new, potentially general protocol for the construction of ring C, and the fragmentation of a β,γ-epoxy ketone to introduce the tertiary OH group at C(13) in the indole diterpene skeleton." @default.
- W2022189912 created "2016-06-24" @default.
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- W2022189912 date "2003-12-01" @default.
- W2022189912 modified "2023-10-18" @default.
- W2022189912 title "Indole-Diterpene Synthetic Studies: Total Synthesis of (−)-21-Isopentenylpaxilline" @default.
- W2022189912 doi "https://doi.org/10.1002/hlca.200390328" @default.
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