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- W2022195910 abstract "Surface tension lowering, equilibrium spreading pressure, and insoluble monolayer data are presented for a homologous series (C8 and C10C19) of alkylbenzyldimethylammonium chlorides (benzalkonium chlorides) in the presence and absence of excess electrolyte. In the presence of excess electrolyte, the surface tension lowering data adhered to Traube's rule; however, in the absence of electrolyte, significant deviation occurred. Surface pressure-molecular area isotherms were constructed from these surface tension lowering data in the ideal region and were compared in order to study the the effect of the electrolyte on the surface film. An “odd-even” chain length effect was seen in the equilibrium spreading pressures of the longer chain homologs. This is explained in terms of the melting point data. Studies of the monolayers formed at the air-water interface by the longer chain homologs were carried out and a molecular orientation in these monolayers is suggested." @default.
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- W2022195910 date "1971-06-01" @default.
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- W2022195910 title "Some interfacial properties of alkylbenzyldimethylammonium chlorides" @default.
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