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- W2022199158 abstract "Abstract 1‐Dimensional halocuprate(I) chains [(Cu 2 X 4 ) 2– ] n (= [(CuX 2 ) – ] n , X = Cl, Br, I) have been synthesized under hydrothermal conditions through in‐situ reduction of Cu II X 2 with Fe II X 2 or as phase pure materials through comproportionation of Cu II X 2 or Cu II O with Cu 0 metal in the presence of the respective aqueous hydrogen halide HX and a templating amine. Chains of trans edge‐sharing tetrahedra are obtained with piperazinium or ethylenediammonium dications, while the 4,4′‐bipyridinium dication gave chains of cis edge‐sharing tetrahedra. Two monoprotonated piperazinium groups act as cationic ligands (Hpipz + ) towards copper atoms in a molecular [Cu 4 (μ‐Br 6 )(Hpipz) 2 ] cluster. Electrical crystal conductivities of the halocuprate [(Cu 2 X 4 ) 2– ] n (= [(CuX 2 ) – ] n ) chains (X = Cl, Br, I) are around 10 –8 S · cm –1 at room temperature." @default.
- W2022199158 created "2016-06-24" @default.
- W2022199158 creator A5030073931 @default.
- W2022199158 creator A5056457936 @default.
- W2022199158 creator A5090644272 @default.
- W2022199158 date "2009-07-01" @default.
- W2022199158 modified "2023-10-01" @default.
- W2022199158 title "Piperazinium, Ethylenediammonium or 4,4′-Bipyridinium Halocuprates(I) by Cu<sup>II</sup>/Cu<sup>0</sup>Comproportionation" @default.
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- W2022199158 doi "https://doi.org/10.1002/zaac.200900091" @default.
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