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• W2022199270 startingPage "6859" @default.
• W2022199270 abstract "An efficient total synthesis of (−)-cis-clavicipitic acid has been achieved in seven linear steps (42% overall yield) from the known compound 6. The present synthesis features a palladium-catalyzed indole synthesis to provide the optically pure 4-chlorotryptophan derivative and a Heck reaction using aryl chloride as partner. It has also been discovered that the key azepinoindole nucleus could be stereoselectively constructed via a Mg(ClO4)2-mediated intramolecular aminocyclization." @default.
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• W2022199270 date "2009-07-29" @default.
• W2022199270 modified "2023-10-09" @default.
• W2022199270 title "Efficient Total Synthesis of (−)-<i>cis</i>-Clavicipitic Acid" @default.
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• W2022199270 doi "https://doi.org/10.1021/jo9012755" @default.
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