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- W2022201185 abstract "Abstract Solid solutions of Li-doped Mg 0.857 Cu 2.143 O 3 (Li x Mg 0.857− x Cu 2.143 O 3− y ) were prepared at 950°C for 12 h in air by the solid-state method using Li 2 CO 3 , MgO and CuO powders. The solid solutions were obtained as the single α phase with the guggenite structure in 0≦ x ≦0.06 region. With the increasing of the Li content x , the lattice parameters a , b and unit cell volume V decreased, while c increased. On the basis of the charge neutrality, hole carrier estimated by the oxygen content increased with the Li substitution. The Seebeck coefficient at room temperature of x = 0.03 sample was +400 μV/K. The electrical resistivity ρ at room temperature drastically decreased with the increasing x. Temperature dependences of ρ for x = 0.01, 0.03 and 0.06 samples were semi-conductive behavior from room temperature to about 12 K. Interaction between Cu 2+ and Cu 2+ through O 2− seems to be somewhat large antiferromagnetic one. Sperconducting transition was not detected in the temperature range." @default.
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- W2022201185 date "2002-10-01" @default.
- W2022201185 modified "2023-09-27" @default.
- W2022201185 title "Synthesis, Crystal Structure and Physical Properties of LixMg0.857−xCu2.143O3−y" @default.
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