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• W2022201966 abstract "Differential scanning calorimetry has been used to determine the excess heat capacity of liquid mixtures of triglyme and tetraglyme with cyclohexane, and tetraglyme with n-heptane, at 288.15, 298.15 and 308.15 K, at atmospheric pressure, throughout the composition range. The curves thus obtained as a function of composition were found to be W-shaped. The results are compared with those for other glyme–alkane mixtures. Changes in the W-shaped curves with temperature were virtually linear for mixtures which have an upper critical solution temperature (UCST) relatively distant from the measuring range; by contrast, excess heat capacities increased asymptotically near the phase separation region. The results are discussed in terms of order creation in the mixture that arises from concentration fluctuations near the UCST." @default.
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• W2022201966 date "1997-01-01" @default.
• W2022201966 modified "2023-09-26" @default.
• W2022201966 title "Excess heat capacities of glyme[ndash ]alkane mixtures Influence of the upper critical solution temperature" @default.
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• W2022201966 doi "https://doi.org/10.1039/a704539e" @default.
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