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- W2022203715 abstract "Raman measurements on solid hydrogen show a maximum in the vibrational frequency of a H2 molecule as a function of pressure, around 350 Kbar. We give an interpretation of this experimental data by considering a model in which a single H2 molecule is immersed in a dielectric medium, and enclosed in a spheroidal box to simulate the effect of pressure. The maximum results from a balance between a decreasing equilibrium bond length of H2 with pressure at low pressures and a term which reflects the pressure dependence of the dielectric constant. Our results are consistent with available calculations which give a much lower vibrational frequency at a much higher pressure, for a H2 molecule embedded in a metallic medium." @default.
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- W2022203715 date "1986-01-01" @default.
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- W2022203715 title "Maximum in vibrational frequency shift of a hydrogen molecule in solid hydrogen under pressure" @default.
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