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• W2022205556 abstract "An efficient method for the synthesis of fused pyrroloheterocycles from diverse propargyl-substituted heterocycles in the presence of Au-catalyst has been developed. The cascade transformation proceeds via alkyne-vinylidene isomerization with concomitant 1,2-shift of hydrogen, silyl, and stannyl groups. Remarkably, it was also shown that previously unknown 1,2-migration of a germyl group upon alkyne-vinylidene rearrangement occurs under these reaction conditions. This method allows for mild and efficient synthesis of diverse C-2 substituted N-containing heterocycles." @default.
• W2022205556 created "2016-06-24" @default.
• W2022205556 creator A5001641190 @default.
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• W2022205556 date "2006-08-24" @default.
• W2022205556 modified "2023-10-14" @default.
• W2022205556 title "Gold-Catalyzed 1,2-Migration of Silicon, Tin, and Germanium en Route to C-2 Substituted Fused Pyrrole-Containing Heterocycles" @default.
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• W2022205556 doi "https://doi.org/10.1021/ja063278l" @default.
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