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- W2022206582 abstract "The solubilities of benzene, toluene, o-, m-, and p-xylenes, and naphthalene in water as well as in aqueous salt solutions were determined at 25° C by spectrophotometry. The salts used were NaF, KF, LiCl, NaCl, KCl, LiBr, NaBr, KBr, NaNO3, NaClO3, NH4Cl, NH4Br, NMe4Br, NEt4Br, (NH4)2 SO4, Na2SO4, K2SO4, MgCl2, SrCl2, BaCl2, MgSO4, HCOONa, CH3COONa, C2H5COONa, C3H7COONa, etc. The activity coefficients of these non-electrolytes, f, have also been calculated. The relationship between log f and Cs (salt concentration, 0–0.8 M) were all found to be straight lines through the origin, in agreement with Setschenow's experimental formula. The salting-out constants of benzene and its derivatives in solutions of the above-mentioned 25 salts have been calculated by the formulas of (a) Debye and MacAulay, (b) Conway et al. (c) McDevit and Long, (d) the scaled particle theory and the scaled particle theory modified by Xie and Yang, and (e) the internal pressure theory modified by Xie et al. The theoretical values obtained from the internal pressure theory modified by Xie seems to coincide with the experimental value better than those from the other theories, but it will be further improved if the van der Waals force, except for the electrostatic force, is also taken into account." @default.
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- W2022206582 date "1990-11-01" @default.
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- W2022206582 title "Studies on the activity coefficient of benzene and its derivatives in aqueous salt solutions" @default.
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- W2022206582 doi "https://doi.org/10.1016/0040-6031(90)80154-q" @default.
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