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- W2022206825 abstract "R)-1-(1-Naphthyl)ethanol is an essential chiral substrate for the synthesis of nonactin and dihydro-(1H)- quinoline-2-one derivatives. Stereoinversion of (S)-1-(1-naphthyl)ethanol to (R)-1-(1-naphthyl)ethanol by whole cell biocatalysis, using Candida parapsilosis, is reported here. Candida parapsilosis possesses a requisite redox system for the stereoinversion of secondary alcohol. The reaction conditions (tempera- ture, time, pH, organic solvent, etc.) significantly influenced the stereoinversion process. Optimum con- ditions were found to be the reaction temperature of 30 C, a cellmass concentration of 200 mg/mL, pH 7 (phosphate buffer, 50 mM), a shaking speed of 200 rpm, and a 12 h reaction time. Under these optimum conditions, (R)-1-(1-naphthyl)ethanol was obtained in 100% eeR and 88% yield." @default.
- W2022206825 created "2016-06-24" @default.
- W2022206825 creator A5008188841 @default.
- W2022206825 creator A5060893790 @default.
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- W2022206825 date "2013-06-01" @default.
- W2022206825 modified "2023-09-25" @default.
- W2022206825 title "One-pot synthesis of (R)-1-(1-naphthyl)ethanol by stereoinversion using Candida parapsilosis" @default.
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- W2022206825 doi "https://doi.org/10.1016/j.tetlet.2013.04.051" @default.
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