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• W2022207647 abstract "Two Co(II) coordination polymers, {[Co(bdc)(bib)(H2O)]·H2O}n (1) and {[Co(bdc)(bibp)]}n (2), where H2bdc = 1,4-benzenedicarboxylic acid, bib = 1,4-bis(1-imidazolyl)benzene, and bibp = 4,4′-bis(imidazolyl)biphenyl, have been synthesized by solvothermal methods and characterized by IR spectra, element analyses, thermal analysis, powder X-ray diffraction, and single crystal X-ray diffraction. Complex 1 exhibits a 3-D pillared-layer framework, the ligands of bib and bdc link Co ions to generate a 2-D layer structure, which is further pillared by the bib, giving the final 3-D pillared-layer networks. The void in 1 induces the three-fold interpenetrating structure. Complex 2 features three-fold interpenetrating 3-D architecture, bdc and bibp both adopt a bidentate bridging coordination to link Co ions to afford right- and left-handed helical chains; these helices fuse together and form the 3-D framework." @default.
• W2022207647 created "2016-06-24" @default.
• W2022207647 creator A5011541056 @default.
• W2022207647 creator A5071987871 @default.
• W2022207647 date "2014-02-16" @default.
• W2022207647 modified "2023-09-27" @default.
• W2022207647 title "Synthesis, crystal structure, and characterization of two three-fold interpenetrating Co(II) coordination polymers based on 1,4-benzenedicarboxylic acid and length modulated bisimidazole ligands" @default.
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• W2022207647 doi "https://doi.org/10.1080/00958972.2014.895822" @default.
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