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- W2022208870 abstract "The graft copolymerization of methyl methacrylate (MMA) onto silk in aqueous media initiated by the potassium peroxydiphosphate-thiourea redox system was studied at 50°C. The rate of grafting was determined by changing [monomerl], [thiourea], [initiator], acidity of the medium, reaction medium, and temperature. A significant increase percent of grafting was noticed with increasing monomer concentration to 84.49 × 10−2 mole/liter and the further increase is associated with the decrease of graft yield. The graft yield increases with an increase of thiourea (Tu) concentration to 25 × 10−5 mole/liter; then it decreases. A measurable increase in graft yield was observed with an increase in acidity of the medium. Graft yield increases to a certain temperature, i.e., 50°C, and then it decreases. The graft yield increases with an increase of initiator concentration to 60 × 10−4 mole/liter; then it decreases. The graft yield is medium dependent. A suitable kinetic path has been proposed and the rate equation has been derived." @default.
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- W2022208870 date "1980-07-01" @default.
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- W2022208870 title "Grafting vinyl monomers onto silk fibers. IX. Graft copolymerization of methyl methacrylate onto silk using peroxydiphosphate-thiourea redox system" @default.
- W2022208870 doi "https://doi.org/10.1002/pol.1980.170180719" @default.
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