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• W2022210207 startingPage "2068" @default.
• W2022210207 abstract "An organometallic/silica nanocomposite of a 1D cylindrical assembly of a trinuclear gold(I)–pyrazolate complex ([Au3Pz3]) that was confined inside the nanoscopic channels of hexagonal mesoporous silica ([Au3Pz3]/silicahex), emitted red light with a luminescence center at 693 nm upon photoexcitation at 276 nm owing to a AuIAuI metallophilic interaction. When a film of [Au3Pz3]/silicahex was dipped into a solution of Ag+ in tetrahydrofuran (THF), the resulting nanocomposite material ([email protected][Au3Pz3]/silicahex) emitted green light with a new luminescence center at 486 nm, which was characteristic of a AuIAgI heterometallic interaction. Changes in the emission/excitation and XPS spectra of [email protected][Au3Pz3]/silicahex revealed that Ag+ ions permeated into the congested nanochannels of [Au3Pz3]/silicahex, which were filled with the cylindrical assembly of [Au3Pz3]." @default.
• W2022210207 created "2016-06-24" @default.
• W2022210207 creator A5044947650 @default.
• W2022210207 creator A5063217261 @default.
• W2022210207 creator A5064060206 @default.
• W2022210207 creator A5087302222 @default.
• W2022210207 date "2012-03-16" @default.
• W2022210207 modified "2023-10-18" @default.
• W2022210207 title "Metal-Ion Permeation in Congested Nanochannels: The Exposure Effect of Ag+ Ions on the Phosphorescent Properties of a Gold(I)-Pyrazolate Complex that is Confined in the Nanoscopic Channels of Mesoporous Silica" @default.
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• W2022210207 doi "https://doi.org/10.1002/asia.201200041" @default.
• W2022210207 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22431445" @default.
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