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- W2022212089 abstract "A general method is described for indirectly effecting radical carbocyclization of an alkyl chain onto an aromatic ring. Birch reductive-alkylation of aromatic tert-butyl esters with α,ω-dibromides, chromium(VI)-mediated oxidation of the resulting 1,4-dienes and Finkelstein displacement of Br− with NaI gives cross-conjugated ketones that undergo radical cyclization. The products are easily aromatized to phenols by silylation, Saegusa oxidation and treatment with BiCl3.H2O. A special feature of the route is that it allows attachment of a substituent to the original aromatic ring in place of the phenolic oxygen of the normal product." @default.
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- W2022212089 date "2008-01-01" @default.
- W2022212089 modified "2023-10-03" @default.
- W2022212089 title "Formal radical closure onto aromatic rings—a general route to carbocycles" @default.
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- W2022212089 doi "https://doi.org/10.1039/b803308k" @default.
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