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- W2022214827 abstract "Surface-enhanced Raman scattering (SERS) spectra of 2-formylpyridine-4′, 4′-dimethyl thiosemicarbazone (DMePATS2) on a silver electrode in acetonitrile electrolytic solution were obtained. The effect of Mg(ClO4)2 on the DMePATS2 adsorption process was investigated. The results show that the configuration of adsorbed DMePATS2 on the silver electrode depends on the applied potential. For negative potentials, the predominant configuration on the surface is E whereas for positive potentials there is almost only the Z isomer. In the presence of Mg2+ only the (Z)-DMePATS2 isomer was observed at any potential, which is explained by the formation of an Mg2+–(E)-DMePATS2 complex in solution. The formation of this complex is also used to explain the decrease in the Raman intensity of the adsorbed species in the time evolution experiment. A comparison is made between the SERS results for DMePATS2 and PATS4 (4-formylpyridine thiosemicarbazone). The SERS spectra of PATS4 in the presence of Mg2+ indicate the formation of an Mg2+–PATS4 complex on the surface. Copyright © 2002 John Wiley & Sons, Ltd." @default.
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- W2022214827 date "2002-01-01" @default.
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- W2022214827 title "Competition between adsorption and complexation on silver as monitored by surface-enhanced Raman scattering" @default.
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- W2022214827 doi "https://doi.org/10.1002/jrs.817" @default.
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