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- W2022222487 abstract "Here, we report a novel synthesis of a monosubstituted, enantio- and diastereomerically enriched trans-cyclononadienol. The reaction consists of an enantioselective (-)-sparteine-mediated allylic lithiation of an achiral 7-chlorononadienyl carbamate and a subsequent stereospecific intramolecular allyllithium-allyl chloride coupling. The stereochemical course of the cyclization has been determined, and the high configurative stability of the chiral nine-membered carbocycle has been investigated by kinetic measurements and rationalized by computational calculations." @default.
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- W2022222487 date "2000-07-12" @default.
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- W2022222487 title "Asymmetric Synthesis of a (2<i>Z</i>,7<i>E</i>)-Cyclononadiene by an Intramolecular Cycloalkylation and Insight to Its Conformational Properties" @default.
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- W2022222487 doi "https://doi.org/10.1021/ol005998h" @default.
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