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• W2022223129 abstract "Abstract A sensitive new pulsed beam cavity microwave Fourier transform spectrometer has been constructed. It has been used to measure for the first time the pure rotational spectra of the van der Waals complexes ArO 13 CS, Ar 18 OCS and Ar 17 OCS, and to measure further transitions of ArOC 34 S. Rotational and centrifugal distortion constants have been determined for all species, as well as 17 O quadrupole coupling constants in Ar 17 OCS. A harmonic force field has been obtained for the van der Walls motions, and has been used to reproduce the variations of distortion constants with isotopomer. Both substitution and ground state average structures have been evaluated. It is confirmed that the complex is a loose binding of Ar and OCS, with little change in the structural parameters of OCS from those of the free molecule." @default.
• W2022223129 created "2016-06-24" @default.
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• W2022223129 date "1992-01-01" @default.
• W2022223129 modified "2023-09-27" @default.
• W2022223129 title "The rotational spectrum of the isotopically substituted van der Waals complex ArOCS, obtained using a pulsed beam microwave Fourier transform spectrometer" @default.
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• W2022223129 doi "https://doi.org/10.1016/0022-2852(92)90016-h" @default.
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