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- W2022225679 abstract "The influence of coke deposited from n-hexane and mesitylene on HZSM5 on the transport characteristics of probe molecules was investigated by measuring both the intracrystalline self-diffusion coefficients and tracer desorption coefficients using NMR methods. Coking with n-hexane involves an initial period in which coke is deposited in the intracrystalline channel network and a final period in which deposition is mainly on the outer surface of the zeolite crystals. In contrast, coke from mesitylene is predominantly deposited on the outer surface of the zeolite crystals from the very beginning. These results are explained by a model of controlled coking which implies that coke deposition is simultaneously determined by the size of the hydrocarbon molecule and the amount of coke already deposited." @default.
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- W2022225679 date "1987-01-01" @default.
- W2022225679 modified "2023-10-18" @default.
- W2022225679 title "Controlled coke deposition on zeolite ZSM5 and its influence on molecular transport" @default.
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- W2022225679 doi "https://doi.org/10.1016/s0166-9834(00)82603-2" @default.
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