Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022232255> ?p ?o ?g. }
- W2022232255 endingPage "1937" @default.
- W2022232255 startingPage "1923" @default.
- W2022232255 abstract "AbstractThree new polymeric Rb(I) salts of trinitrophenol and trinitroresorcinol, rubidium trinitrophenol ([RbTNP]n), bi-substituted rubidium salt of trinitroresorcinol ([Rb2TNR·H2O]n), and mono-substituted rubidium salt of trinitroresorcinol ([RbHTNR]n) were synthesized and characterized by X-ray single-crystal diffraction, elemental analysis, and IR spectroscopy. The central Rb(I) cations are 10 or 11-coordinated by oxygens from nitro group, phenolic hydroxyl and coordinated water, and the multidentate ligands bridged different Rb(I) centers. Coordination bonds, electrostatic interaction, and intermolecular hydrogen bonds assemble the ions into 3-D polymeric network structures. Thermal decomposition behaviors of the compounds were studied by applying differential scanning calorimetry under various linear heating rates. Sensitivities measurements revealed that these compounds are sensitive to flame, insensitive to impact and friction stimulates. All properties show that the compounds are promising to be an eco-friendly initiating composition, especially [RbTNP]n.Three rubidium salts of trinitrophenol and trinitroresorcinol were obtained and characterized in this article. Thermal behaviors and sensitivities investigation confirmed them to be promising heat-resistant flame sensitive eco-friendly initiator composition.Keywords: Rubidium saltsTrinitrophenolTrinitroresorcinolCrystal structureProperties AcknowledgementsThis work was supported by the National Basic Research Program of China, the Natural Science Foundation of Chongqing (cstc2011jjA50013) and the Doctoral Candidate Innovation Research Support Program by Science & Technology Review (kjdb201001-2)." @default.
- W2022232255 created "2016-06-24" @default.
- W2022232255 creator A5001232753 @default.
- W2022232255 creator A5012015418 @default.
- W2022232255 creator A5017760263 @default.
- W2022232255 creator A5047988740 @default.
- W2022232255 creator A5048204687 @default.
- W2022232255 creator A5053470501 @default.
- W2022232255 creator A5080276547 @default.
- W2022232255 date "2014-06-03" @default.
- W2022232255 modified "2023-10-09" @default.
- W2022232255 title "Syntheses, crystal structures, thermal behaviors, and sensitivities of new initiator compositions: rubidium salts of trinitrophenol and trinitroresorcinol" @default.
- W2022232255 cites W1419421433 @default.
- W2022232255 cites W1964740351 @default.
- W2022232255 cites W1966116471 @default.
- W2022232255 cites W1973367883 @default.
- W2022232255 cites W1979553621 @default.
- W2022232255 cites W1990808932 @default.
- W2022232255 cites W1997882020 @default.
- W2022232255 cites W1998332850 @default.
- W2022232255 cites W1998839019 @default.
- W2022232255 cites W2003780056 @default.
- W2022232255 cites W2007009115 @default.
- W2022232255 cites W2007298338 @default.
- W2022232255 cites W2007514272 @default.
- W2022232255 cites W2008854263 @default.
- W2022232255 cites W2011602559 @default.
- W2022232255 cites W2029032315 @default.
- W2022232255 cites W2034496408 @default.
- W2022232255 cites W2042465985 @default.
- W2022232255 cites W2042873168 @default.
- W2022232255 cites W2046104536 @default.
- W2022232255 cites W2052854085 @default.
- W2022232255 cites W2058860892 @default.
- W2022232255 cites W2094201662 @default.
- W2022232255 cites W2101504766 @default.
- W2022232255 cites W2126715447 @default.
- W2022232255 cites W2131350133 @default.
- W2022232255 cites W2152507203 @default.
- W2022232255 cites W2186717420 @default.
- W2022232255 cites W2335431623 @default.
- W2022232255 cites W4231231689 @default.
- W2022232255 cites W4232159282 @default.
- W2022232255 cites W4239266928 @default.
- W2022232255 cites W4245938683 @default.
- W2022232255 cites W98511255 @default.
- W2022232255 doi "https://doi.org/10.1080/00958972.2014.932353" @default.
- W2022232255 hasPublicationYear "2014" @default.
- W2022232255 type Work @default.
- W2022232255 sameAs 2022232255 @default.
- W2022232255 citedByCount "2" @default.
- W2022232255 countsByYear W20222322552015 @default.
- W2022232255 countsByYear W20222322552016 @default.
- W2022232255 crossrefType "journal-article" @default.
- W2022232255 hasAuthorship W2022232255A5001232753 @default.
- W2022232255 hasAuthorship W2022232255A5012015418 @default.
- W2022232255 hasAuthorship W2022232255A5017760263 @default.
- W2022232255 hasAuthorship W2022232255A5047988740 @default.
- W2022232255 hasAuthorship W2022232255A5048204687 @default.
- W2022232255 hasAuthorship W2022232255A5053470501 @default.
- W2022232255 hasAuthorship W2022232255A5080276547 @default.
- W2022232255 hasConcept C112887158 @default.
- W2022232255 hasConcept C115624301 @default.
- W2022232255 hasConcept C121332964 @default.
- W2022232255 hasConcept C147789679 @default.
- W2022232255 hasConcept C153642686 @default.
- W2022232255 hasConcept C160434732 @default.
- W2022232255 hasConcept C166950319 @default.
- W2022232255 hasConcept C178790620 @default.
- W2022232255 hasConcept C179104552 @default.
- W2022232255 hasConcept C185592680 @default.
- W2022232255 hasConcept C2776371256 @default.
- W2022232255 hasConcept C2778087735 @default.
- W2022232255 hasConcept C32909587 @default.
- W2022232255 hasConcept C39519442 @default.
- W2022232255 hasConcept C517785266 @default.
- W2022232255 hasConcept C526903357 @default.
- W2022232255 hasConcept C8010536 @default.
- W2022232255 hasConcept C97355855 @default.
- W2022232255 hasConceptScore W2022232255C112887158 @default.
- W2022232255 hasConceptScore W2022232255C115624301 @default.
- W2022232255 hasConceptScore W2022232255C121332964 @default.
- W2022232255 hasConceptScore W2022232255C147789679 @default.
- W2022232255 hasConceptScore W2022232255C153642686 @default.
- W2022232255 hasConceptScore W2022232255C160434732 @default.
- W2022232255 hasConceptScore W2022232255C166950319 @default.
- W2022232255 hasConceptScore W2022232255C178790620 @default.
- W2022232255 hasConceptScore W2022232255C179104552 @default.
- W2022232255 hasConceptScore W2022232255C185592680 @default.
- W2022232255 hasConceptScore W2022232255C2776371256 @default.
- W2022232255 hasConceptScore W2022232255C2778087735 @default.
- W2022232255 hasConceptScore W2022232255C32909587 @default.
- W2022232255 hasConceptScore W2022232255C39519442 @default.
- W2022232255 hasConceptScore W2022232255C517785266 @default.
- W2022232255 hasConceptScore W2022232255C526903357 @default.
- W2022232255 hasConceptScore W2022232255C8010536 @default.
- W2022232255 hasConceptScore W2022232255C97355855 @default.
- W2022232255 hasIssue "11" @default.