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- W2022235170 abstract "The rarity of occurrence of cis peptide units is only partially explained by the higher intrinsic energy of the cis over the trans form, which provides a probability of 0·01 for cis peptide units to occur. An additional factor is the conformational restriction imposed by the occurrence of a cis peptide unit in a chain of trans units. Taking a section of three peptide units having the sequences trans-trans-trans (ttt) and trans-cis-trans (tct), conformational energy calculations indicate that the latter can occur only to an extent of 0·1%, unless there occurs the sequence X-Pro, in which case it is of the order of 30%. This explains the extreme rarity of cis peptide units, in general; however, it follows that even with non-prolyl residues, cis peptide units are not forbidden, but can occur in some rare examples and should be looked for." @default.
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- W2022235170 date "1976-10-01" @default.
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- W2022235170 title "An explanation for the rare occurrence of cis peptide units in proteins and polypeptides" @default.
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- W2022235170 doi "https://doi.org/10.1016/s0022-2836(76)80019-8" @default.
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