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- W2022236142 abstract "A novel iron-catalyzed aerobic oxidative reaction to synthesize disubstituted isoxazoles from homopropargylic alcohol, t-BuONO, and H2O is developed. The method provides mild conditions to afford a variety of useful substituted heterocycles in an efficient and regioselective manner. The mechanism has been studied and proposed, which indicates that the transformation can be realized through construction of a C═N bond and C═O bond, C–H oxidation, and then cyclization. Moreover, this method can be enlarged to gram scale." @default.
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- W2022236142 date "2014-11-26" @default.
- W2022236142 modified "2023-10-18" @default.
- W2022236142 title "Facile Synthesis of Disubstituted Isoxazoles from Homopropargylic Alcohol via C═N Bond Formation" @default.
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- W2022236142 doi "https://doi.org/10.1021/ol503228x" @default.
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