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• W2022237573 abstract "The Abramov reaction, a base-catalyzed nucleophilic addition of dialkyl H-phosphonates (phosphites) to carbonyl compounds, was performed with oxidized quinine derivatives as the substrates. Homologous aldehydes obtained from the vinyl group reacted in a typical way which led to α-hydroxyphosphonates, first reported compounds containing a direct P-C bond between the quinine carbon skeleton and a phosphorus atom. For the C9 ketones a phosphonate-phosphate rearrangement, associated with a tandem elimination of the piperidine fragment, was evidenced." @default.
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• W2022237573 date "2014-04-17" @default.
• W2022237573 modified "2023-10-16" @default.
• W2022237573 title "Addition of <i>H</i>-phosphonates to quinine-derived carbonyl compounds. An unexpected C9 phosphonate–phosphate rearrangement and tandem intramolecular piperidine elimination" @default.
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• W2022237573 doi "https://doi.org/10.3762/bjoc.10.85" @default.
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