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- W2022240954 abstract "The flash photolysis of di-μ-oxo bis(oxo-molybdenum(V)) complexes in aqueous solutions of perchloric acid in the presence of excess chloride induced both photolabilization and photo-oxidation of Cl− and/or H2O ligands. Photolabilization produces the formation of reaction intermediates identified as μ-oxo-bis (oxo-molybdenum(V)) species: Mo2O2(μ-O)(H2O)84+ (A) and Mo2O2(μ-O)(Cl)(H2O)73+ (B). A rapid equilibria between the transient species is established before they decay through a first order reaction. Intermediate A is the only species effective in promoting the observed decay leading to Mo(VI) and H2 as end products. The relative absorption spectrum of species B is reported, as well as its stability constant in the temperature range 25–45 °C. The effect of ligands on the overall mechanism is discussed." @default.
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- W2022240954 date "1993-01-01" @default.
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- W2022240954 title "The flash photolysis of di-μ-oxo-bis(oxo-molybdate(V)) acid aqueous solutions in the presence of excess chloride" @default.
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