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- W2022241778 abstract "A set of ligands bearing 6-bromo-2,2'-bipyridine pendant arms attached in the 5'-position are described. Transformation of the bromo to an ester was performed by a carboethoxylation reaction promoted by low-valent Pd(0), while saponification followed by acidification gave the acids. The introduction of an appended function 3-nitrobenzyl, benzamidomethyl, and tert-butylacetyl opens the way to further functionalize these scaffolds for potential labeling of biological material. The synthetic protocols represent a valuable approach to the rational design of ligands bearing oxophilic and anionic sidearms." @default.
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- W2022241778 date "2002-05-01" @default.
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- W2022241778 title "5‘-Substituted-6-carboxylic-2,2‘-bipyridine Acid: A Pivotal Architecton for Building Preorganized Ligands" @default.
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- W2022241778 doi "https://doi.org/10.1021/jo0200015" @default.
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