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- W2022242443 abstract "Crystals of VM9O25(M = Nb, Ta) have been grown by a self-flux method. The crystal structures have been determined from X-ray single crystal diffraction data. Both compounds are isostructural and crystallize in the tetragonal PNb9O25 structure type, I4̄, with unit-cell parameters a = 15.690(2) Å, c = 3.8172(9) Å, Vol. = 939.7(3) Å3, form = Nb;and a = 15.665(6), c = 3.821(3), Vol. 937.6(9) for M = Ta; and Z = 2. The crystal structure of tridimensional VM9O25 is formed by a singular combination of two VO4 tetrahedra and eighteen MO6 octahedra per unit-cell. The presence of oxygen nonstoichiometry in VNb9O25 is studied." @default.
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- W2022242443 date "1993-01-01" @default.
- W2022242443 modified "2023-10-18" @default.
- W2022242443 title "VM9O25(M = Nb, Ta), a Combination of Tetrahedral VO4 and Octahedral MO6 Units" @default.
- W2022242443 doi "https://doi.org/10.1006/jssc.1993.1030" @default.
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