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- W2022243444 abstract "Abstract Ground state chlorine atoms have been generated photochemically to study the attack on hydrogen in the CH2Cl group, or deuterium in the CD2Cl group, as a function of deuterium substitution in the vicinal methyl group of a number of ethyl chloride molecules. The experiments were carried out in the gas phase, at temperatures 9–95°C, using methane as competitor (kr). Rate constants for the following reactions are reported: The temperature dependences of the relative rate constants ki/kr were found to obey the Arrhenius rate law:" @default.
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- W2022243444 date "1984-11-01" @default.
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- W2022243444 title "Secondary kinetic isotope effects in hydrogen and deuterium abstraction by chlorine atoms from the chloromethyl group in gaseous ethyl chlorides: effects of isotopic substitution in the adjacent methyl group" @default.
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