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- W2022244089 abstract "Abstract High-resolution X-ray absorption spectroscopy (XAS) has been applied to the study of the electronic interaction of interstitial N2 molecules with the surface oxide matrix of an oxidized TiAlN film. The Nπ* feature of the interstitial N2 molecules has displayed evident vibrational fine structure, on which the full width at half maximum lifetime width (Γ) and vibrational separation (ωe) have been calculated. The comparison of the Γ value with that of gaseous phase N2 molecules has shown that theπ* orbital of the N2 molecules has a very weak electronic interaction with the orbitals of the matrix. In addition, the change in theωe value has suggested that the N N bonding of the N2 molecules is strengthened due to the stress by the surrounding matrix." @default.
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- W2022244089 date "1998-03-01" @default.
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- W2022244089 title "High-resolution XAS spectrum of interstitial nitrogen molecules in the surface oxide matrix of TiAlN film" @default.
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- W2022244089 doi "https://doi.org/10.1016/s0368-2048(97)00215-6" @default.
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