Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022244110> ?p ?o ?g. }
- W2022244110 endingPage "18660" @default.
- W2022244110 startingPage "18651" @default.
- W2022244110 abstract "The synthesis and photophysical properties of an ethynylphenyl-substituted terpyridine ligand L and its corresponding zinc(II) complex [Zn(L)2](PF6)2, serving as model compounds for self-assembling Zn(II)-based metallopolymers suited for photoluminscent and electroluminescent devices, are presented. The UV−vis spectra are characterized, and the photoluminescence quantum yields are determined. The ground-state structures are calculated by means of DFT, and the structural key features are approved by experimental as well as by DFT-calculated Raman spectra. Special attention is paid to the π-electron delocalization between phenylene (ph) and pyridine (py) and, in particular, to changes in the ph−py bond due to complexation. The DFT-calculated ph−py bond shortening in [Zn(L)2](PF6)2 compared to L correlates well with the higher wavenumber of the v(ph−py(trig)) vibration, which involves strong ph−py bond stretching. The higher ellipticity in the ph−py bond due to complexation, calculated according to Bader’s QTAIM indicating the π-character of a bond, is confirmed by the higher Raman intensity of the v(ph−py(trig)) vibration. The electron density distributions in the ph−py bond between [Zn(L)2](PF6)2 and L are compared in an inter−Δρ plot, which highlights the changes in the bonding situation of the ph−py bond induced by complex forming." @default.
- W2022244110 created "2016-06-24" @default.
- W2022244110 creator A5002938368 @default.
- W2022244110 creator A5025570395 @default.
- W2022244110 creator A5038818054 @default.
- W2022244110 creator A5055566096 @default.
- W2022244110 creator A5070808413 @default.
- W2022244110 creator A5071143262 @default.
- W2022244110 creator A5085286783 @default.
- W2022244110 creator A5087026021 @default.
- W2022244110 date "2008-10-31" @default.
- W2022244110 modified "2023-10-16" @default.
- W2022244110 title "Zinc(II) Bisterpyridine Complexes: The Influence of the Cation on the π-Conjugation between Terpyridine and the Lateral Phenyl Substituent" @default.
- W2022244110 cites W141356951 @default.
- W2022244110 cites W1487183720 @default.
- W2022244110 cites W1966137223 @default.
- W2022244110 cites W1966545431 @default.
- W2022244110 cites W1966894540 @default.
- W2022244110 cites W1967292966 @default.
- W2022244110 cites W1969144422 @default.
- W2022244110 cites W1970544868 @default.
- W2022244110 cites W1973513120 @default.
- W2022244110 cites W1973650318 @default.
- W2022244110 cites W1980532895 @default.
- W2022244110 cites W1987538300 @default.
- W2022244110 cites W1992478560 @default.
- W2022244110 cites W1992856935 @default.
- W2022244110 cites W1997010639 @default.
- W2022244110 cites W1998613997 @default.
- W2022244110 cites W2001277223 @default.
- W2022244110 cites W2001547233 @default.
- W2022244110 cites W2001898241 @default.
- W2022244110 cites W2004442858 @default.
- W2022244110 cites W2005286482 @default.
- W2022244110 cites W2006008657 @default.
- W2022244110 cites W2012689397 @default.
- W2022244110 cites W2013440762 @default.
- W2022244110 cites W2016430343 @default.
- W2022244110 cites W2016800344 @default.
- W2022244110 cites W2017110163 @default.
- W2022244110 cites W2017619667 @default.
- W2022244110 cites W2020379489 @default.
- W2022244110 cites W2024073153 @default.
- W2022244110 cites W2025821805 @default.
- W2022244110 cites W2028022118 @default.
- W2022244110 cites W2030687437 @default.
- W2022244110 cites W2033945824 @default.
- W2022244110 cites W2034913146 @default.
- W2022244110 cites W2036022839 @default.
- W2022244110 cites W2040886879 @default.
- W2022244110 cites W2042062103 @default.
- W2022244110 cites W2048883495 @default.
- W2022244110 cites W2050440875 @default.
- W2022244110 cites W2050606126 @default.
- W2022244110 cites W2052648626 @default.
- W2022244110 cites W2056553878 @default.
- W2022244110 cites W2058210956 @default.
- W2022244110 cites W2061409599 @default.
- W2022244110 cites W2063003654 @default.
- W2022244110 cites W2063900353 @default.
- W2022244110 cites W2064657631 @default.
- W2022244110 cites W2065655440 @default.
- W2022244110 cites W2065874228 @default.
- W2022244110 cites W2071453097 @default.
- W2022244110 cites W2076565660 @default.
- W2022244110 cites W2083532388 @default.
- W2022244110 cites W2085327878 @default.
- W2022244110 cites W2085405112 @default.
- W2022244110 cites W2086957099 @default.
- W2022244110 cites W2089216507 @default.
- W2022244110 cites W2092408086 @default.
- W2022244110 cites W2092522778 @default.
- W2022244110 cites W2095917356 @default.
- W2022244110 cites W2097158264 @default.
- W2022244110 cites W2121973206 @default.
- W2022244110 cites W2124908200 @default.
- W2022244110 cites W2126554223 @default.
- W2022244110 cites W2141074519 @default.
- W2022244110 cites W2141645913 @default.
- W2022244110 cites W2142817638 @default.
- W2022244110 cites W2160989746 @default.
- W2022244110 cites W2215137360 @default.
- W2022244110 cites W2317604061 @default.
- W2022244110 cites W2329949269 @default.
- W2022244110 cites W2502302781 @default.
- W2022244110 cites W29179573 @default.
- W2022244110 cites W2949140933 @default.
- W2022244110 cites W3005288840 @default.
- W2022244110 cites W4229676205 @default.
- W2022244110 cites W4321428221 @default.
- W2022244110 doi "https://doi.org/10.1021/jp807461j" @default.
- W2022244110 hasPublicationYear "2008" @default.
- W2022244110 type Work @default.
- W2022244110 sameAs 2022244110 @default.
- W2022244110 citedByCount "37" @default.
- W2022244110 countsByYear W20222441102012 @default.
- W2022244110 countsByYear W20222441102013 @default.
- W2022244110 countsByYear W20222441102014 @default.