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• W2022245636 endingPage "4827" @default.
• W2022245636 startingPage "4824" @default.
• W2022245636 abstract "X‐ray absorption spectra of chlorine K edge, ruthenium LIII edge, and rhodium LIII edge from (NH4)3[RhCl6], K3[RuCl6], and [Ru(NH3)6]Cl3 have been measured with a Johann‐type 50 cm bent crystal vacuum spectrograph. The white lines due to the transitions to the incompletely filled antibonding molecular orbital (MO) 2t2g(π*) or nonbonding orbital t2g and the empty antibonding MO 3eg(σ*) for the octahedral complexes have been observed in the Cl K edge, Ru LIII edge, and Rh LIII edge regions. It is found that the two absorption peaks at the Ru LIII edge reflect the ligand‐field effect. An interpretation for experimental results of the Cl K edge and the Ru LIII edge absorption spectra in K3RuCl6 on the basis of the MO scheme leads us to the conclusion that the white lines at the Cl K edge suffer from the effect of core hole." @default.
• W2022245636 created "2016-06-24" @default.
• W2022245636 creator A5043721697 @default.
• W2022245636 creator A5062546016 @default.
• W2022245636 creator A5085758237 @default.
• W2022245636 date "1986-05-01" @default.
• W2022245636 modified "2023-09-26" @default.
• W2022245636 title "X‐ray absorption near‐edge structure of complex compounds (NH₄)₃RhCl₆, K₃RuCl₆, and Ru(NH₃)₆Cl₃" @default.
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• W2022245636 doi "https://doi.org/10.1063/1.449970" @default.
• W2022245636 hasPublicationYear "1986" @default.
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