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- W2022247055 abstract "A study has been carried out in vitro on the chelating properties of several dithiocarbamates derived from α-amino acids (glycine, DL-alanine, DL-valine, DL-leucine, DL-isoleucine, and L-proline) against Pb(II) and Cd(II). The general formulae of the complexes obtained was M(dtc a.a.), where M = Pb(II), Cd(II), and (dtc a.a.) stands for the dithiocarbamate derivative. The infrared spectra show characteristic absorption bands, especially those originated by stretching modes of CN, CS, NH, and COO− moieties, in addition to other vibrations due to the hydrocarbon chains. Electronic spectroscopy has been used to evaluate the association constants of the complexes larger than 109. A slight decomposition of the dithiocarbamate molecules is observed during formation of the complexes, depending both on the nature of the dithiocarbamate and the nature of the cation, being more pronounced for Cd(II) than for Pb(II)." @default.
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- W2022247055 date "1991-04-01" @default.
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- W2022247055 title "Dithiocarbamates derivatives from α-amino acids as chelating agents for toxic metal ions" @default.
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- W2022247055 doi "https://doi.org/10.1016/0162-0134(91)80028-g" @default.
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