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- W2022247652 abstract "Goodwin−Lions-type sp2N/sp3N hybrid ligands R-BINAN-R‘-Py possessing a C2 axis binaphthyl skeleton have been designed and synthesized. Combination of the new non-phosphine ligand with Ru(π-CH2C(CH3)CH2)2(cod) has been revealed to catalyze the hydrogenation of aromatic ketones with high enantioselectivity of up to 99% ee. The reaction proceeds essentially without the need for any bases, but the reactivity is enhanced by the addition of KOt-C4H9 attaining an S/C ratio of up to 10 000. The success should expand the range of possibilities in designing catalysts not only for hydrogenation but also for many other reactions." @default.
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- W2022247652 date "2006-06-20" @default.
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- W2022247652 title "Enantioselective Hydrogenation of Aromatic Ketones Catalyzed by Ru Complexes of Goodwin−Lions-type sp<sup>2</sup>N/sp<sup>3</sup>N Hybrid Ligands R-BINAN-R‘-Py" @default.
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- W2022247652 doi "https://doi.org/10.1021/ja062451a" @default.
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