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• W2022248274 abstract "Zn1-xMgxO alloy formation via band gap engineering is important in the development of blue−UV optoelectronic devices by providing lattice-matched transparent substrates for ZnO and nitride-related devices. Zn1-xMgxO alloy single crystals (Zn0.97Mg0.03O and Zn0.945Mg0.055O) have been successfully grown by the hydrothermal technique. The growth experiments were carried out at 650 °C and 15−18 kpsi in alkaline solutions. Zn1-xMgxO alloy crystals were formed at pressures below ∼22 kpsi at the growth temperature of 650 °C. These conditions are similar to the formation of MgO under hydrothermal conditions. A thin ZnO layer formed on the surface of the ZnMgO crystals as the autoclaves cooled to room temperature. After the ZnO layer was removed by etching or polishing from both the Zn0.97Mg0.03O and Zn0.945Mg0.055O samples, blue shifts of the photoluminescence emission from the 3.364 eV line of pure ZnO to 3.414 and 3.447 eV, respectively, were measured at ∼18 K. The composition of the alloys was confirmed by using secondary ion mass spectroscopy (SIMS) elemental analysis. X-ray diffraction indicated that the alloy crystals have good structural quality, whereas the lattice parameters are smaller than those of pure ZnO (for Zn0.945Mg0.055O a = 3.2416 Å, c = 5.1998 Å) because the radius of Mg2+ is smaller than that of Zn2+." @default.
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• W2022248274 date "2006-05-10" @default.
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• W2022248274 title "Hydrothermal Growth and Photoluminescence of Zn₁_-<i>_x</i>Mg<i>_x</i>O Alloy Crystals" @default.
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• W2022248274 doi "https://doi.org/10.1021/cg0504004" @default.
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