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- W2022250355 abstract "The differential scanning calorimeter heating curves of uniaxially oriented poly(ethylene terephthalate) (PET) fibers with three peaks were analyzed by using a newly proposed equation. The diffusion-controlled crystallization theory is suitable for describing cold crystallization of uniaxially oriented PET fibers. A crystallization model was proposed based on the kinetic parameters obtained. The model embraces the three sub-processes of crystallization corresponding to different growth geometries. The first sub-process corresponds to the nucleation of ordered molecular segments or the radial growth of preformed nucleus, resulting in the shorter bundle-like entities. The second sub-process corresponds to further growth of the bundle-like crystallites along chain direction, resulting in the longer bundle-like entities. The third sub-process corresponds to the three-dimensional growth of crystallites relating to the random segments, resulting in the spherical entities." @default.
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- W2022250355 date "2004-06-01" @default.
- W2022250355 modified "2023-10-18" @default.
- W2022250355 title "Model of cold crystallization of uniaxially oriented poly(ethylene terephthalate) fibers" @default.
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- W2022250355 doi "https://doi.org/10.1016/j.polymer.2004.04.046" @default.
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