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- W2022251088 startingPage "2142" @default.
- W2022251088 abstract "The proton acid-catalyzed decomposition of 3-aryl-2-diazo-3-hydroxy-1-phenylpropanone (1) gave aryl and hydrogen migration products. The former was the enol-form (2) of 2-aryl-3-phenyl-1,3-propanedione and the latter was the enol- (3) and keto-form (4) of 1-aryl-3-phenyl-1,3-propanedione. The product ratios, 2/(3+4), were affected by the catalysts and solvents used. More polar solvents favored the formation of aryl migration products (2). On the other hand, the BF3-catalyzed decomposition of 1 gave acetylenic ketones as main products along with 2, 3, and 4. The TsOH-catalyzed decomposition of 2-diazo-3-hydroxy-3-phenyl-1-indanone, (cyclic α-diazo β-hydroxy ketone), gave 2-phenyl-1,3-indandione quantitatively through phenyl migration." @default.
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- W2022251088 date "1981-07-01" @default.
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- W2022251088 title "The Acid-catalyzed Decomposition of α-Diazo β-Hydroxy Ketones" @default.
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- W2022251088 doi "https://doi.org/10.1246/bcsj.54.2142" @default.
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