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• W2022252483 abstract "The layered cobaltites ${mathrm{La}}_{2ensuremath{-}x}{mathrm{Sr}}_{x}mathrm{Co}{mathrm{O}}_{4}$ have been complexly studied over the range of mixed ${mathrm{Co}}^{3+∕4+}$ valency and their properties discussed in comparison with cubic perovskites ${mathrm{La}}_{1ensuremath{-}x}{mathrm{Sr}}_{x}mathrm{Co}{mathrm{O}}_{3}$. The sample $x=1.0$ exhibits a paramagnetic ground state based on the intermediate spin state of ${mathrm{Co}}^{3+}$ and undergoes a broad resistivity transition at $400--900phantom{rule{0.3em}{0ex}}mathrm{K}$, associated with diffusive changes of magnetic susceptibility and volume expansion. The ${mathrm{Co}}^{4+}$ doping in samples with $x>1$ induces gradually ferromagnetism and leads to a dramatic decrease of resistivity and thermopower, though the metallicity is not achieved. The neutron diffraction on the limit composition $x=1.4$ suggests that the long-range ordered ferromagnetic regions coexist with paramagnetic ones, and their amount changes little with an application of high pressures up to $4.3phantom{rule{0.3em}{0ex}}mathrm{GPa}$." @default.
• W2022252483 created "2016-06-24" @default.
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• W2022252483 date "2006-10-19" @default.
• W2022252483 modified "2023-09-27" @default.
• W2022252483 title "Structural, magnetic, and transport properties of the single-layered perovskites<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mi mathvariant=normal>La</mml:mi><mml:mrow><mml:mn>2</mml:mn><mml:mo>−</mml:mo><mml:mi>x</mml:mi></mml:mrow></mml:msub><mml:msub><mml:mi mathvariant=normal>Sr</mml:mi><mml:mi>x</mml:mi></mml:msub><mml:mi mathvariant=normal>Co</mml:mi><mml:msub><mml:mi mathvariant=normal>O</mml:mi><mml:mn>4</mml:mn></mml:msub></…" @default.
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• W2022252483 doi "https://doi.org/10.1103/physrevb.74.134414" @default.
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