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• W2022252965 abstract "This study presents a mathematical formalism describing diffraction effects from periodic and mixed-layer minerals in which the outer surface layers of crystals possibly differ from layers forming the core of the crystals. The X-ray diffraction (XRD) patterns calculated for structure models of chlorite and irregular chlorite-smectites terminated on both sides of the crystals by either brucite-like sheets or 2:1 layers show the strong influence that different outer surface layers have on the distribution of basal reflection intensities. Simulation of the experimental XRD patterns from two chlorite samples having different Fe contents shows that in these two samples the chlorite crystals were terminated by brucite-like sheets on both sides. In contrast, crystals in a corrensite sample were terminated by water molecules and exchangeable cations. The nature of diffraction effects due to outer surface layers is discussed." @default.
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• W2022252965 date "2004-12-01" @default.
• W2022252965 modified "2023-10-18" @default.
• W2022252965 title "Influence of the Outer Surface Layers of Crystals on the X-Ray Diffraction Intensity of Basal Reflections" @default.
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• W2022252965 doi "https://doi.org/10.1346/ccmn.2004.0520602" @default.
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