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- W2022254232 abstract "A new catalytic synthesis of the Wong’s antracyclines intermediate, (R)-2-acetyl-2-hydroxy-5,8-dimethoxy-1,2,3,4-tetrahydronapthlene, starting from the corresponding 1,2-diol has been discovered through its selective hydrogenolysis in the presence of palladium heterogeneous catalysts. High yield and no racemization were found under mild reaction conditions: the molar selectivity towards the target product was always higher than 99.5%. The catalytic performances resulted strongly dependent on the nature of the palladium catalyst, unreduced Pd/C showing the best performances. This straightforward catalytic route significantly improves the up to now adopted industrial process." @default.
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- W2022254232 date "2006-11-01" @default.
- W2022254232 modified "2023-10-09" @default.
- W2022254232 title "Catalytic hydrogenation for the industrial synthesis of the Wong’s anthracyclines intermediate" @default.
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- W2022254232 doi "https://doi.org/10.1016/j.catcom.2006.03.022" @default.
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