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- W2022256862 abstract "Abstract In addition to being a very good antioxidant, γ‐tocopherol is also an excellent electrophile trap. This is a study of the reactivity of γ‐tocopherol with hypochlorous acid/hypochlorite, a potential biological foe that is both an oxidant and an electrophile. Aqueous sodium hypochlorite (1.72 mmol; pH 7.4) was stirred with γ‐tocopherol (0.12 mmol) in hexane for 2 min at room temperature. The following products were isolated: γ‐tocopheryl quinone (0.6%), tocored (10%), 3‐chloro‐γ‐tocopheryl quinone (14%), an ether dimer of 3‐chloro‐γ‐tocopheryl quinone (0.4%), two isomers of 5‐(5‐γ‐tocopheryl)‐γ‐tocopherol (3 and 2% respectively), 5‐chloro‐γ‐tocopherol (14%) and two chlorinated dimers (14 and 24% respectively) which were identified as diastereomers of (3 R ,10 R )‐11a‐chloro‐2,3,9,10‐tetrahydro‐3,5,6,10,12,13‐hexamethyl‐3,10‐ bis [(4 R ,8 R )‐4,8,12‐trimethyltridecyl]‐1 H ‐pyrano(3,2a)‐8 H ‐pyrano(3,2g)‐dibenzofuran‐14(7a H )(14a H )‐one. The chlorinated dimers, 5‐chloro‐γ‐tocopherol, 3‐chloro‐γ‐tocopheryl quinone and its ether dimer are new compounds." @default.
- W2022256862 created "2016-06-24" @default.
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- W2022256862 date "2007-01-27" @default.
- W2022256862 modified "2023-09-29" @default.
- W2022256862 title "Reaction of γ-Tocopherol with Hypochlorous Acid" @default.
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- W2022256862 doi "https://doi.org/10.1007/s11745-006-3016-2" @default.
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