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- W2022259994 abstract "The self-assembly of the title dinuclear complex, namely (mu-p-phenylenediamine-N,N,N',N'-tetraacetato)bis[aqua(1,10-phenanthroline)nickel(II)] dodecahydrate, [Ni(2)(C(14)H(12)N(2)O(8))(C(12)H(8)N(2))(2)(H(2)O)(2)].12H(2)O, through intricate noncovalent interactions results in a two-dimensional sheet-like structure. The dimer lies about an inversion centre at the centre of the p-phenylenediamine ring. Uncoordinated water molecules form one-dimensional chains in which cyclic water tetramers act as two types of building blocks. The water molecules play a significant role in the stabilization of the three-dimensional supramolecular framework. Intramolecular ;aryl-metal chelate ring' pi-pi interactions are also observed." @default.
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- W2022259994 date "2007-10-13" @default.
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- W2022259994 title "Formation of a one-dimensional water chain containing two linking patterns of planar water tetramers" @default.
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- W2022259994 doi "https://doi.org/10.1107/s0108270107047294" @default.
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