Matches in SemOpenAlex for { <https://semopenalex.org/work/W2022262488> ?p ?o ?g. }
- W2022262488 endingPage "2590" @default.
- W2022262488 startingPage "2590" @default.
- W2022262488 abstract "Recently, a small number of diverse iridium complexes have been shown to catalyze unusual atom transfer C–H functionalization reactions. To further our understanding and enhance the utility of iridium complexes for C–H functionalization, we report the design and synthesis of a family of iridium(III)-bis(oxazolinyl)phenyl complexes. The ability to tune the ligand environment around the metal in these systems is exploited to design complexes with the ability to catalyze the asymmetric insertion of donor/acceptor iridium carbenoids into activated C–H bonds. Low catalyst loadings (0.5 mol%) routinely lead to excellent reaction yields (51–99%) and enantioselectivities (83–99%). Density functional theory calculations provide compelling evidence that in these complexes the carbene binds to the iridium cis to the phenyl group of the bis(oxazolinyl)phenyl ligand. This finding is vital for understanding the observed stereochemical induction and is of particular significance in the field of enantioselective transition metal-catalysed atom transfer reactions utilizing oxazoline–X–oxazoline tridentate ligands, as previously employed stereochemical models for these ligand sets are based on the assumption that reactive ligands and Lewis bases bind trans to the central X ligand." @default.
- W2022262488 created "2016-06-24" @default.
- W2022262488 creator A5012743614 @default.
- W2022262488 creator A5031746021 @default.
- W2022262488 creator A5052669292 @default.
- W2022262488 creator A5062485768 @default.
- W2022262488 creator A5071095861 @default.
- W2022262488 creator A5083948798 @default.
- W2022262488 date "2013-01-01" @default.
- W2022262488 modified "2023-10-16" @default.
- W2022262488 title "Iridium(iii)-bis(oxazolinyl)phenyl catalysts for enantioselective C–H functionalization" @default.
- W2022262488 cites W125452486 @default.
- W2022262488 cites W1964284609 @default.
- W2022262488 cites W1965821414 @default.
- W2022262488 cites W1966182479 @default.
- W2022262488 cites W1969457598 @default.
- W2022262488 cites W1970194400 @default.
- W2022262488 cites W1976801308 @default.
- W2022262488 cites W1981390016 @default.
- W2022262488 cites W1984232099 @default.
- W2022262488 cites W1986842517 @default.
- W2022262488 cites W1990483095 @default.
- W2022262488 cites W1994238881 @default.
- W2022262488 cites W1995035753 @default.
- W2022262488 cites W1997151511 @default.
- W2022262488 cites W1999250336 @default.
- W2022262488 cites W1999403268 @default.
- W2022262488 cites W2000012466 @default.
- W2022262488 cites W2011776106 @default.
- W2022262488 cites W2013665598 @default.
- W2022262488 cites W2013711777 @default.
- W2022262488 cites W2018536426 @default.
- W2022262488 cites W2019573388 @default.
- W2022262488 cites W2025470822 @default.
- W2022262488 cites W2032808909 @default.
- W2022262488 cites W2033817758 @default.
- W2022262488 cites W2038293290 @default.
- W2022262488 cites W2040041008 @default.
- W2022262488 cites W2041159135 @default.
- W2022262488 cites W2046935766 @default.
- W2022262488 cites W2049824282 @default.
- W2022262488 cites W2050554411 @default.
- W2022262488 cites W2050791488 @default.
- W2022262488 cites W2051778076 @default.
- W2022262488 cites W2056768233 @default.
- W2022262488 cites W2057233246 @default.
- W2022262488 cites W2060296131 @default.
- W2022262488 cites W2061142370 @default.
- W2022262488 cites W2063913713 @default.
- W2022262488 cites W2066309940 @default.
- W2022262488 cites W2086589980 @default.
- W2022262488 cites W2090280264 @default.
- W2022262488 cites W2093196338 @default.
- W2022262488 cites W2094447616 @default.
- W2022262488 cites W2097186155 @default.
- W2022262488 cites W2099127406 @default.
- W2022262488 cites W2102838682 @default.
- W2022262488 cites W2103172054 @default.
- W2022262488 cites W2124370725 @default.
- W2022262488 cites W2126700974 @default.
- W2022262488 cites W2127484472 @default.
- W2022262488 cites W2147925478 @default.
- W2022262488 cites W2149115397 @default.
- W2022262488 cites W2149630320 @default.
- W2022262488 cites W2150195378 @default.
- W2022262488 cites W2151882027 @default.
- W2022262488 cites W2153701075 @default.
- W2022262488 cites W2155587860 @default.
- W2022262488 cites W2160572359 @default.
- W2022262488 cites W2164631251 @default.
- W2022262488 cites W2170261800 @default.
- W2022262488 cites W2314372106 @default.
- W2022262488 cites W2316525374 @default.
- W2022262488 cites W2327540458 @default.
- W2022262488 cites W2329690651 @default.
- W2022262488 cites W4237056151 @default.
- W2022262488 doi "https://doi.org/10.1039/c3sc50886b" @default.
- W2022262488 hasPublicationYear "2013" @default.
- W2022262488 type Work @default.
- W2022262488 sameAs 2022262488 @default.
- W2022262488 citedByCount "47" @default.
- W2022262488 countsByYear W20222624882013 @default.
- W2022262488 countsByYear W20222624882014 @default.
- W2022262488 countsByYear W20222624882015 @default.
- W2022262488 countsByYear W20222624882016 @default.
- W2022262488 countsByYear W20222624882017 @default.
- W2022262488 countsByYear W20222624882018 @default.
- W2022262488 countsByYear W20222624882019 @default.
- W2022262488 countsByYear W20222624882020 @default.
- W2022262488 countsByYear W20222624882021 @default.
- W2022262488 countsByYear W20222624882022 @default.
- W2022262488 crossrefType "journal-article" @default.
- W2022262488 hasAuthorship W2022262488A5012743614 @default.
- W2022262488 hasAuthorship W2022262488A5031746021 @default.
- W2022262488 hasAuthorship W2022262488A5052669292 @default.
- W2022262488 hasAuthorship W2022262488A5062485768 @default.
- W2022262488 hasAuthorship W2022262488A5071095861 @default.
- W2022262488 hasAuthorship W2022262488A5083948798 @default.