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- W2022265123 abstract "Metal-coordinated “γ-lactam-capped” and “imide-capped” 1,10-phenanthroline ligands are reported. Whereas the imide-functionalized ligand 1,10-phenanthroline-5,6-carboximide could not be obtained as a free ligand, probably due to its extremely low solubility, we developed a protocol to first introduce the more soluble 1,10-phenanthrolino[5,6-c]pyrrole in the ligand sphere of cyclometalated iridium(III) complexes, followed by the oxidation of the pyrrole moiety to a maleimide utilizing a peroxybenzoic acid. The hydrogen bond donor–acceptor properties of the new ligands should make them suitable building blocks for the design of metal-based protein binders. Furthermore, we unexpectedly found that bis-cyclometalated iridium(III) complexes coordinated to 1,10-phenanthroline-5,6-carboximide display luminescence properties that are dependent on the protonation state of the maleimide NH group. It can be envisioned to exploit this behavior for the real-time monitoring of hydrogen bonding interactions in biological systems." @default.
- W2022265123 created "2016-06-24" @default.
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- W2022265123 date "2014-09-01" @default.
- W2022265123 modified "2023-09-23" @default.
- W2022265123 title "Novel metal-coordinated 1,10-phenanthroline ligands functionalized with a lactam or imide" @default.
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- W2022265123 doi "https://doi.org/10.1016/j.ica.2014.07.008" @default.
- W2022265123 hasPublicationYear "2014" @default.
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