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- W2022267723 abstract "The radio-frequency spectra of HF and H35Cl in an external electric and magnetic field are measured using a high-resolution molecular-beam electric-resonance spectrometer. The measurements are in the lowest vibrational state (v = 0) and the first rotational state (J = 1). The spectra are analyzed using a standard Hamiltonian. The magnetic properties of the molecules are derived using methods introduced by Ramsey. The results, corrected for the effects of molecular vibrations, are: HFH35ClgJ0.74104(15)0.45935(9)χ| - χδ (kHz/(kG)2)0.132(6)−0.048(18)(χ| - χδ)d (10−6erg/G2·mole)1.342(25)3.49(10)(σ| - σδ)H (ppm)24(9)21(5)(σ| - σδ)Hd (ppm)−96(9)−148(7)(σ| - σδ)hal (ppm)108(9)300(24)(σ| - σδ)hald (ppm)−1(9)−4(25)θ (10−26esu cm2)2.36(3)3.74(12) Numbers in parentheses are the errors in the final significant figures. Generally good agreement is found with existing ab initio calculations." @default.
- W2022267723 created "2016-06-24" @default.
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- W2022267723 date "1973-12-01" @default.
- W2022267723 modified "2023-10-16" @default.
- W2022267723 title "Magnetic properties and molecular quadrupole moment of HF and HCl by molecular-beam electric-resonance spectroscopy" @default.
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